Hi Jane,
Your tree is suffering from deficiency, but the question is whats causing it. I don't mean what element is your tree lacking, I mean whats blocking the absorption of that element. There is a chance its just lacking, but your comments about water quality are alarming/complicating from a diagnostic standpoint.
I would test your pH at about 5" down to rule out alkalinity blocking micro and macro nutrient absorption. I would also test your NPK levels. You can typically pick up these types of test kits around 20 bucks
online. You'll want the test kits with the capsules, and Leaf Luster products have worked well for me regarding around the house testing.
My only concern is the source of alkalinity in your water, because if it's from high calcium, that can block absorption or transfer of certian nutrient like magnesium. In fact over abundants of several elements can block absorption or assimilation of other essential nutrients leading to deficiency symptoms. So by increasing nutrients based on leaf diagnosis of the deficit element, without proper tests, can sometimes only increas the problem and increase unnecessary salts in the soil biome harming the one source that best feeds the flora.
Anyway once you've ruled out pH being off, and over/under application of N, P and K, it would be safe to supplement with some liquid kelp and epsom salt. Just follow the directions on the liquid kelp bottle for mixing up 2 gallons of kelp mix, then add in a tablespoon of Epsom salt. Make sure your tree is well watered, then add the supplement mix evenly to your soil. If its a mobile macro nutrient like Nitrogen, which could be indicated by unaffected green tips, and deficent older leaves, just fertalize accordingly. A standard application of any ballenced or specific NPK ratio for targeting that deficiency can be foiler
feed to work quickly, and organic options are available. A foliar feed is the best bet to curb deficiency, while waiting for any ammendments on the soil to kick in.
If your pH is high, thats the first issue you'll need to address. It won't be a fast solution as it typically takes time to use some supplements that lower pH, as its commonly a bacterial process utilizing sulfer which makes the pH alteration as a byproduct of digestion within the biome. My guess if its high pH, it is a build up of alkaline salts in your soil most likely from high calcium. You'll need to find a better souce of water like rain catchment or a Reverse Osmosis filter to stop that issue from reoccurring. With just good quality rain water for flushing those exess minerals, it will start leaching those salts out, which should start to reverse the process. Deep infrequent waterings when needed are best, verses frequent shallow waterings.
Other options are available to help alter your pH, but you'll need to have quality water, and way to easily test pH, like a pH meter. If you do, you can mix a solution of ACV with your water to a pH of 6.5, and use that to flush salts with deep waterings. It will help flush the salts, and counter the alkalinity, while giving slight pH adjustments when you water helping bringing your pH back to normal. Once you've determined oz per gallon of ACV for the proper water pH, you can use a garden hose fertalizer mixer/applicator to do those deep waterings at proper ratio.
Im sure you have lots of other questions, but that's my best suggestions to should get you started.