(copied with permission)
TOXIC CARDBOARD: An organic gardening expose
By Andy Firk
Boy oh boy, corrugated fiberboard boxes sure are a common sight to see. "Over three quarters of all perishable goods are being shipped in some sort of a cardboard box or corrugated fiberboard container." (J) Now, all cardboards MAY not necessarily contain toxins, but from my research, the vast, vast majority sure do, and holy crap, do they contain some toxins! The percentage of non-toxic cardboard on the market is very low, and quite a mystery to unravel. Just where to obtain such pure cardborad may be difficult or nearly impossible to figure out, as I have learned this week. I have been calling a few of our state's cardboard manufacturing facilities, and I continue to find more chemical processing steps in the manufacturing. Little information is offered up easily by these companies. These manufacturers do not openly discuss the proprietary ingredients used in the manufacturing of cardboard materials. This should be enough information for an organically-inclined person with average intelligence to keep them away from their gardens. From use of cardboard as an under-mulch layer, to a cover for blocking weeds in pathways, there is a commonly held misconception that cardboard is benign, safe, non-toxic, and biodegradable. Nothing could be further from the natural truth. If you are not convinced, please read on.
WHERE DOES THE WOOD PULP MIX FOR CARDBOARD COME FROM?
The pulping process of making paper pulp for cardboard often contains horrible chemicals. Some of the worst polluters in the country are pulp mills. One pulp mill, the Buckeye Pulp Mill, who supplies pulp for corrugated fiberboard among other products, releases enormous levels of DIOXIN into the Gulf Of Mexico, here in Florida. It is ranked as one of the worst polluters in the entire state, if not the worst in terms of certain chemicals being released. Numerous articles and studies attest to this "should-be-closed" mill. The Clean Water Network Of Florida published a concise article a few years back. (G) "According to the 2005 TRI (Toxics Release Inventory), Buckeye reported releasing 240,630 pounds of known cancer-causing toxics, those recognized by OSHA as being carcinogens, to the air and water." (G) In total "Buckeye admitted emitting 19,537,806 pounds of toxics to the EPA's 2005 TRI, ranking Buckeye the most polluting pulp or paper mill in Florida." "Buckeye has been in operation for 53 years, polluting the environment, contaminating the fish, and poisoning the air and water with hundreds of very dangerous toxics." (G) Pulp for cardboard is one part of this nightmare for Taylor County residents. But let's move on to the specifics of cardboard, especially "corrugated fiberboard", or "wavy cardboard".
RSC, THE MOST COMMON TYPE OF CARDBOARD BOX
"The most common box style is the Regular Slotted Container (RSC)." "The manufacturer's joint is most often joined with ADHESIVE." (B) What, if any chemical toxins are an ingredient in this adhesive? I wasn't sure until I started digging for information.
FORMALDEHYDE
Some community gardens have ruled out the use of toxic cardboard, siting the FORMALDEHYDE ingredient. Though this is debated. (A) Not much information about FORMALDEHYDE in cardboard is available, so let's move on to what we know IS in cardboard.
MANUFACTURING STEPS
Lets examine the manufacturing steps that it takes to make a "natural-looking" sheet of wavy cardboard (aka Corrugated Fiberboard)
SULFATE PROCESS
"Fast-growing pine trees provide the primary raw material used to make corrugated cardboard." "At the mill, the harvested tree trunks are subjected to the "Kraft Process", also known as the "SULFATE PROCESS" because of the CHEMICALS used to break down wood chips into fibrous pulp." (I) SULFATE, SO4, is CONTAMINATING our waters near these mills.
POSSIBLE CHEMICALS IN THE PULPING PROCESS
"The manufacturing process begins with pulping, the separation of wood (hardwood and sapwood) into individual fibers, as accomplished by mechanical methods or CHEMICAL treatment." (wiki / 4)
TOXIC SODIUM HYDROXIDE
"First, tree trunks are stripped of bark and torn into small chips. Next, these chips are placed in a large, high-pressure tank called a BATCH DIGESTOR, where they are cooked in a solution, or liquor, made of SODIUM HYDROXIDE (NaOH) and several other ionic compounds such as SULFATES, SULFIDES, and SULFITES. These STRONGLY ALKALINE CHEMICALS dissolve the lignin, the glue-like substance that holds the individual wood fibers together in a tree trunk." "When the pressure is released after several hours, the wood chips explode like popcorn into fluffy masses of fiber." (I)
CHEMICALS IN THE CORN STARCH GLUE
It is a total myth among organic gardeners and permaculturists that CORN STARCH GLUE in cardboard is non-toxic. "CORN STARCH GLUE is used to bond the corrugated medium to the liner sheets. Because so much GLUE is used, rail cars or large tanker trucks deliver it as a dry powder that will be stored in huge silos at the corrugating plant until it is needed. Drawn from the silo, the dry corn starch is mixed with water and OTHER CHEMICALS." "The medium travels next to a set of rollers called the SINGLE-FACER GLUE STATION. Here, one layer of liner is GLUED to the medium. STARCH GLUE is carefully applied to the corrugated edges of the medium, and the first layer of liner is added. From the single-facer, the medium and liner go to the DOUBLE-BACKER GLUE STATION where the other layer of liner from the bridge is added following the same procedure. Continuing through the corrugator, the cardboard passes over steam-heated plates that cure the GLUE." (I) So, you're still not sure if corrugated fiberboard is toxic, then just drive past one of these plants, I have. The stench is unbelievable.
CARCINOGENIC PARAFFIN FROM THE OIL INDUSTRY MAY COAT CARDBOARD BOXES
"Other raw materials are used to finish the corrugated cardboard after production. WAXES made from PARAFFIN or vegetable oils can be applied to make a water-, or grease-resistant container for food products." "Other equipment in a corrugating plant includes... machines known as CURTAIN COATERS that apply a WAX coating to fruit, vegetable, and meat containers." (I)
TOXIC INKS?
On some cardboard boxes "BRIGHTLY COLORED INKS are also applied to create bold graphic designs for self-supporting displays featuring product name, information, and company name and logo." "Today, in the corrugated cardboard industry, designers are creating innovative containers that require FOUR-COLOR PRINTING and complex die-cutting." "Today, inks based on soybean oil and biodegradable waxes and other coatings are BEGINNING to be used in container manufacturing." (I) Are these currently used inks toxic? I would guess, yes. Ah, what the heck, I'll go all out and say, yes they are. Prove me wrong!
LINERBOARDS ARE "PAPER-LIKE"
They are the flat sheets that hold the wavy sheet in place. (B) "Linerboard is made of containerboard", defined by the industry as a "PAPER-LIKE material". (B) These broad ingredient definitions leave legal room for the addition of proprietary CHEMICAL ingredients. "Linerboards are test liners (recycled paper) or kraft paperboard (of various grades)." (wiki)
LINERBOARDS MAY BE MADE FROM "KRAFT-PAPER", WHICH IS OFTEN MADE FROM CHEMICAL PULP
Kraft paperboard is described here (D) and is said to be "paper produced from CHEMICAL PULP processed by the kraft process." (wiki / D) "The raw material is normally softwood pulp from the kraft process. Kraft paper can be white or brown depending on the pulp if it is BLEACHED or unbleached." (wiki / D) "The liner may be BLEACHED WHITE, MOTTLED WHITE, COLORED...." (wiki) And remember, just because a cardboard box looks brown and "natural", is no indication as to its level of BLEACHING in the processing steps.
"RESINS" IN CARDBOARD CAN BE SYNTHETIC / ARTIFICIAL RESINS
"Resin - plant sap, particularly from the pine family. Natural resin tends to be unstable due to its properties. SYNTHETIC RESIN is produced by POLYMERIZATION which then results in the PRODUCTION OF POLYMERS since they are more homogeneous and their properties are more predicable and industrially viable." (J)
ADDITIONAL "LAMINATE LINERS" MAY BE ADDED TO INCREASE STRENGTH OR HEAT AND/OR WATER RESISTANCE
"Heat or water-resistant corrugated fiberboard has an ADDITIONAL LAMINATE LINER applied." (J)
LINERBOARD GLUE (aka ATTACHMENT) MAY CONTAIN TOXINS
The corrugated medium "is joined to a flat linerboard with a STARCH-BASED ADHESIVE." (wiki) "From the paper mill, rolls of kraft paper are transported to a corrugating, or converting, plant. At the plant, layers of kraft paper are crimped and GLUED to form corrugated cardboard." "At the beginning of this process, kraft rolls from the paper mill are loaded into a huge machine called a CORRUGATOR." "Some rolls of kraft paper are used as the corrugating medium, and others are used as liners, the layers of kraft paper GLUED on each side of the medium. After the CORRUGATOR has heated, GLUED, and pressed the kraft paper to form corrugated cardboard, the continuous sheet of cardboard is cut into wide box blanks that then go to other machines for PRINTING, cutting, and GLUING." (I) Do we know if any toxic chemicals are an ingredient in this adhesive? I'm not sure. Again, I would assume so.
TOXINS IN PRINTING OR COLORING?
"The liner may be... COLORED, or PREPRINTED." (wiki) I do not have information on these additives.
POSSIBLE TOXINS IN THE SURFACE TREATMENTS AND COATINGS
"Corrugated fiberboard can be specified by" various processes including "SURFACE TREATMENTS and COATINGS." (wiki)
THINK RECYCLED CARDBOARD IS A BETTER CHOICE? THINK AGAIN
"Swedish researchers have determined that health issues as minor as inflammation and as and as serious as cancer may be linked to cardboard packaging made from recycled newspapers." "Scientists are linking the health risks to the mineral oils in newspaper ink that survive the recycling process." Recycled from what, other toxic cardboard products? "Researchers at the Food Safety Laboratory in Zurich tested 119 products from German supermarkets, with 90 of the packages containing unsafe levels of MINERAL OILS." "The Food and Drink Federation of the UK has called for an investigation to determine potential long term effects." (H) "Recycled material GENERALLY CONTAINS traces of INKS, ADHESIVES and OTHER CONTAMINANTS which have to be taken into account when determining the product strength and print-quality characteristics. BLEACHING THE PULP is a process aimed at improving print quality but it requires further processing and prolongs the manufacturing cycle." (J)
IN CONCLUSION
So, go ahead and lay down cardboard in the form of "corrugated fiberboard" in your garden rows, or underneath your mulch. Just don't call your garden organic, and be fully prepared to sit down to a lovely meal of toxic veggies, veggies that have systemically absorbed proven carcinogens through their roots. Products that require many processing steps can be assumed to contain chemicals that we are not aware of initially. Take for example the well-intentioned, concerned folks who have been buying BPA-free Plastics as of late. Well as it unsurprisingly turns out, "another report earlier this month revealed that BPA-free plastics, thought to be more stable and safer, have been shown to also leach toxins into foods." (H) Remember the precautionary principle - a product or chemical must be proven safe BEFORE it is assumed safe.
TO RECAP, LET'S JUST LOOK AT THE LIST OF POSSIBLE PROBLEMS
1 - Dioxin
2 - Formaldehyde
3 - Sulfates
4 - Sodium Hydroxide
5 - Sulfides
6 - Sulfites
7 - Corn Starch Glue With Added Chemicals
8 - Paraffin Wax
9 - Toxic Inks
10 - Chemical Pulp
11 - Bleaches
12 - Synthetic / Artificial Polymer Resins
13 - Unknown Laminate Liners
14 - Starch-Based Adhesive Glues
15 - Surface Treatments
16 - Coatings
17 - Toxins From The Recycling Process Including "Mineral Oils" and "Other Contaminants"
18 - The Other Unkowns, including the common use of the generic term "Chemicals" in most of the industry articles that I have read.
STILL DON'T BELIEVE THAT IT IS TOXIC?
If you want to stand up for the commonly held, incorrect belief that corrugated fiberboard is biodegradable and non-toxic, then please prove me wrong. Contact TAPPI, the Technical Association of the Pulp And Paper Industry (E), or ASTM, the American Society For Testing And Materials (F) , and just try getting some information to the contrary from these tight-lipped corporate whores, I dare you.
REFERENCES
A -
http://perrone.blogs.com/horticultural/2008/02/i-recently-had.html B -
http://en.wikipedia.org/wiki/Corrugated_cardboard C -
http://www.thomasnet.com/articles/materials-handling/cardboard-manufacturing D -
http://en.wikipedia.org/wiki/Kraft_paper E -
http://en.wikipedia.org/wiki/TAPPI F -
http://en.wikipedia.org/wiki/ASTM G -
http://www.cleanwaternetwork-fl.org/content/disp_article.php?f=issues/032807_dioxin_joyezell.html H -
http://www.oomphorganic.com/2011/04/cardboard-toxins.html I -
http://www.answers.com/topic/corrugated-cardboard-1 (This is a very in depth description of the processing steps that it takes to make corrugated fiberboard.)
J -
http://www.largecardboardboxes.net/