Judson Carroll wrote:
Tereza Okava wrote:
The article suggests using 50%+ alcohol. I have access to vodka or cachaça (38%ish). Do I just assume that it won't last as long, or do you suppose there is some other consequence of using lower proof spirits?
Lower proof spirits are just fine for bitters.
I agree with this, and I have what I imagine to be an explanation, too.
Bitters (which are really just tinctures of bitter things, usually mixed with other flavors to make them more interesting or pleasant) are typically made, like tinctures, with a 50% solution of alcohol and
water (which is another way of saying "100-proof vodka".) Both water and alcohol are effective solvents, but they dissolve different things or they dissolve the same things with different degrees of effectiveness. So mixing them 50/50 is a way to maximize the power of your solution to suck all the essential goodness out of your herbs and
roots.
You could run the spectrum from pure water (you'd lose some preservative effect and have to take care that your solutions didn't mold or ferment) to pure alcohol (well, 95% is as high as the average consumer can get) and all that would happen is that your flavors would change some (because different amounts of different essentials would be extracted) and you might get less flavor out (because mostly alcohol or mostly water might be less effective at dissolving your particular essentials). So it's an efficiency issue pretty much. But meanwhile back at the ranch, any distilled spirits, even fairly low-proof ones, will work because you're still harnessing the synergistic effect of having two different solvents working away at your expensive, precious, delicious herbal material. A ten or twenty percent imbalance in the alcohol/water ratio isn't going to be that important at the end of the day.
That's how it's been explained to me. I've made a lot of tinctures and extracts with 100-proof vodka (usually as the first step toward making liqueurs) and with 80-proof (40%) and I can't tell the difference. So I think it's all good.